Lviv -> Lwów (for God's sake, don't use the Ukrainian name in the time it wasn't used at all. I understand you use names for some cities in English, but please, do this one in Polish. Please)
Bahahahahaha the poles' wet dream will finally come true xD
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In Brazil:
*Captaincy -> Captaincy-General (Or Capitania Geral, if you want it in native language)
Captaincy here generally refers to the hereditary ones dating back in 1532, adding the -General avoids confusion.
*Sao Salvador -> Salvador (Some like to add the "Sao" for whatever reason... It was no longer the official name for a while when the 7YW came by. In addition, the correct form is "São", not "Sao")
*Continent of Sao Peter -> Rio Grande do Sul
Never heard about this name...
*Captaincy of Para -> Captaincy-General of Grão-Pará (east)
Pará is a modern day state. Back then, it was called 'Grão-Pará" (lit. Greater Pará) that engulfed all the brazilian amazonia.
*Sao Luís -> São Luís
*Rio Negro jungle -> Captaincy-General of Grão-Pará (west)
Well, I can't say the name isn't accurate, but it definetely isn't a province/administrative name, and it's not common in any way :P Alternatively, you can just use "Brazilian Amazonia".
*Recife should be a part of Pernambuco (it's the state capital) and definetely worth less than Salvador. Salvador was the capital (AND SHOULD STILL BE! >:C), and Recife's golden age was over since the dutch gave them the finger and left. In fact, in a couple more years, Bahia would steal all of western Pernambuco from them ^w^
*State of Brasil vs State of Grão-Pará and Maranhão?
This division never existed. Might make them both united on one superbonus. Also for whatever reason São Luís is not part of it...
*Cities Value*
Assuming your goal is historical accuracy and not balancement (hinted by the standalone bonuses that are cities), the value of the cities seems off in every way.
On a scale of power back in the day:
1st: São Paulo (industrial center of the country, had a golden age starting very soon after the seven years war)
2nd: Rio de Janeiro (ugh, this huge slum -.- anyway, back then it was the political center of the country, which strenghtened up it's power, being one of the first big cities in here)
3rd: Salvador (glorious be the real capital, it was a very large city; not particularly rich, just extremely large)
4th: Recife (as soon as the dutch left them, the city went to shit)
5th: Belém (important natural harbor and estuary, wasn't very big but was definetely much richer than all of the northwest and quite above average living conditions for the time)
6th: São Luís (another shitpile built by frenchmen we regret conquering, home to a bunch of corrupt politicians since the dawn of time, wasn't rich nor big, several cities in the northeast deserve it's spot more)
7th: Asunción (despite the jesuits being basically a religious illuminati at the time, the moment they ditched indirect influence to direct control, they broke apart; the jesuit attempt to build a state was killed off in two years, most of this time spent ignoring them because they were claiming land nobody wanted/cared about, only when they started actually growing that something was done; was still very easy)
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Outside of Brazil:
Government of Antioquia -> Government of Antiquoia (Antioquia is the turkish city in the levant, Antioch in english. Antiquoia is the city in Colombia. Also, I'm not really sure if "Government" is an accurate way to describe their provincial system...)
Also, their cities are awfully overpowered o_O though you might want a local to discuss that, since I don't really know much about the rest of latin american history.